Yes, you can!

Shopify B2B orders have a puchasing_entity field.

So in this case, you would simply create a Data Settings for a regular "Order" data type and include these purchasing_entity fields (more info).

You can then use the Custom Filters > User-Defined Fields section in the Data Settings to filter the orders and only include those that have these purchasing_entity fields in your CSV/Excel export.

On the "Templates" page, we also have a pre-built template called "Shopify B2B Orders (Last 30 Days)" which already has all these configured and can be customized further.